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Bug: Assignment rule

Hi, It seems there is bug in assignment rule

These rules work fine:
Purchase order -> Assign condition: status == “To Receive and Bill”
Material request -> Assign condition: material_request_type == “Purchase” and status == “Pending”

These rules does not work:
Purchase order -> Unassign condition: status != “To Receive and Bill”
Material request -> Unassign condition: status != “Pending”

It seems assignment rules cannot work at all with some doctypes. Example these rules does not result in any Todo created:
Purchase receipt -> Assign condition: status == “To Bill”

Would appreciate you help to test on your system.
Is it user error on my side, or is it a bug?
Im on ERPnxt v12.5.2

Many thanks